Evaluation of Processes Affecting 1,2-Dibromo-3-Chloropropane (DBCP) Concentrations in Ground Water in the Eastern San Joaquin Valley, California: Analysis of Chemical Data and Ground-Water Flow and Transport Simulations

Future use of the sole-source aquifer near Fresno in the eastern San Joaquin Valley, California, will depend, in part, on how long 1,2-dibromo-3-chloropropane (DBCP), an agricultural fumigant banned from use since the late 1970’s, persists at concentrations greater than the maximum contaminant level of 0.2 micrograms per liter (?g/L). Field data indicate that DBCP concentrations in ground water have decreased since the late 1970’s. Laboratory experiments by earlier investigators show that DBCP transformed to 2-bromoallyl alcohol (BAA) under conditions similar to in situ conditions, with an estimated half-life ranging from 6.1 (pH 7.8, 21.1 degrees Celsius) to 141 years (pH 7.0, 15 degrees Celsius). For this current study, a detailed hydrogeologic investigation was done to assess the relative importance of chemical transformation, dispersion, and ground-water pumping and reapplication of irrigation water in affecting DBCP concentrations.

Groundwater samples were collected from 20 monitoring wells installed along a 4.6- kilometer transect. DBCP concentrations in these samples ranged from less than the detection limit of 0.03  g/L to a maximum of 6.4 g/L. Results of chlorofluorocarbon (CFC) age dating indicate that DBCP occurs in water that ranges in age from about 2 to 41 years. The primary transformation product BAA, which was identified during previous laboratory studies, was not detected at or greater than 0.03  g/L in any of the 20 ground- water samples. The lack of detection of BAA indicates that transformation to BAA is insignificant relative to other processes controlling DBCP concentrations. Results from this current study indicate that the in situ hydrolysis half-life for DBCP to BAA is much greater than the laboratory-determined values.