Basin-scale responses of groundwater-resource quality to drought and recovery, San Joaquin Valley, California

Hydrological Processes (Wiley) | April 15th, 2024

Groundwater-resource quality is assumed to be less responsive to drought compared to that of surface water due to relatively long transit times of recharge to drinking-su

Groundwater-resource quality is assumed to be less responsive to drought compared to that of surface water due to relatively long transit times of recharge to drinking-supply wells. Here, we evidence dynamic perturbations in aquifer pressure dynamics during drought and subsequent recovery periods cause dramatic shifts in groundwater quality on a basin scale. We used a novel application of time-series clustering on annual nitrate anomalies at >450 public-supply wells (PSWs) across California's San Joaquin Valley during 2000–22 to group subpopulations of wells with similar water-quality responses to drought. Additionally, we statistically evaluated the direction and magnitude of multi-constituent water-quality changes across the San Joaquin Valley using a broader dataset of >3000 PSWs with data during two select hydrologic stress periods representing an extreme drought (2012–16) and subsequent recovery (2016–19). Results of time-series clustering and stress-period change analyses corroborate a predominant regional response to pumping stress characterized by increased concentrations of anthropogenic constituents (nitrate, total dissolved solids) and decreased concentrations of geogenic constituents (arsenic, fluoride), which largely reversed during recovery. Cluster analysis also identified a secondary, less commonly occurring group of PSWs where nitrate decreased during drought, but explanatory factor analysis was not able to discern hydrogeologic drivers for these two divergent response patterns. Long-term tracer data support the hypothesis that the predominant regional signal of nitrate increase during drought is caused by enhanced capture of modern-aged groundwater by PSWs during periods of pumping stress, which can drive rapid changes in water quality on seasonal and multiannual timescales. Pumping-induced migration of modern, oxic groundwater to depth during drought may affect geochemical conditions in deeper portions of regional aquifers controlling the mobility of geogenic contaminants over the long term.

California Groundwater Ambient Monitoring and Assessment (GAMA) Program Priority Basin Project: Domestic-Supply Assessment

U.S. Geological Survey (USGS) | March 14th, 2024

Comparing domestic and public-supply groundwater quality in the northern San Joaquin Valley, 2019—California GAMA Priority Basin Project

U.S. Geological Survey (USGS) | June 5th, 2023

Groundwater quality in the Northern San Joaquin Valley region of California was studied as part of California State Water Resources Control Board (SWRCB) Groundwater Ambi

Groundwater quality in the Northern San Joaquin Valley region of California was studied as part of California State Water Resources Control Board (SWRCB) Groundwater Ambient Monitoring and Assessment Program-Priority Basin Project (GAMA-PBP). The GAMA-PBP made a spatially unbiased assessment of the aquifer system used for domestic drinking-water supply in the study region and compared the results to the aquifer system used for public drinking-water supply. These assessments characterized the quality of raw groundwater to evaluate ambient conditions in regional aquifers and not the quality of treated drinking water. The study included two components: (1) a status assessment presenting study results summarizing the status of groundwater quality used for domestic supply in the Northern San Joaquin Valley and (2) a comparative assessment of groundwater resources used for domestic and public drinking-water supply in the study region.

Comparing Domestic and Public-Supply Groundwater Quality in the Northern San Joaquin Valley, 2019: California GAMA Priority Basin Project

U.S. Geological Survey (USGS) | June 5th, 2023

Analysis of construction data for wells included in the comparative assessment indicated that, although depth to top of perforations are comparable for domestic and publi

Analysis of construction data for wells included in the comparative assessment indicated that, although depth to top of perforations are comparable for domestic and public-supply wells in the Northern San Joaquin Valley (median depth about 60 meters [m]), public-supply wells have longer perforation intervals and extend to deeper parts of the aquifer system (exceeding 120 m) than domestic wells that typically draw exclusively from the shallower aquifer system in the upper 80 m of unconsolidated sediments. Analysis of the vertical and lateral distribution of constituents of interest (nitrate, fumigants, and arsenic) across domestic- and public-supply aquifers indicated that nitrate is prevalent in shallow aquifers throughout the Northern San Joaquin Valley but is potentially diluted by mixing with deeper, older groundwater at long-screened public-supply wells. Fumigants were prevalent in areas of urban and agricultural land use in the western part of the Northern San Joaquin Valley, particularly in areas near Lodi, California, but 1,2,3-TCP was more widespread than DBCP and was detected in shallow and deeper parts of the aquifer system, potentially because of its recalcitrance in groundwater and ability to be detected at low concentrations. Arsenic was most prevalent in the western part of the Northern San Joaquin Valley with proximity to deltaic sediments and was detected at high RCs in wells tapping shallow and deep parts of the aquifer system.

Comparing Groundwater Quality in Public-Supply and Shallow Aquifers in the Monterey Bay and Salinas Valley Basins, California

U.S. Geological Survey (USGS) | December 17th, 2018

Groundwater quality in the Monterey–Salinas Valley Public-Supply and Shallow Aquifer Systems was investigated by the GAMA-PBP. The Monterey–Salinas Valley Pub

Groundwater quality in the Monterey–Salinas Valley Public-Supply and Shallow Aquifer Systems was investigated by the GAMA-PBP. The Monterey–Salinas Valley Public-Supply Aquifer System study unit (MS-PA) initially was assessed in 2005 (Kulongoski and Belitz, 2011). The Mon-terey–Salinas Valley Shallow Aquifer System study unit (MS-SA) was sampled in 2012–13 (Burton and Wright, 2018). The MS-PA and the MS-SA largely coincide areally; however, they represent different parts of the aquifer system vertically. The MS-PA examined deeper groundwater primarily used for public supply, whereas the MS-SA examined relatively shallow groundwater primarily used for domestic supply. The MS-SA was divided into four study areas. Three of these study areas combined (MS-SA3) were equivalent to the MS-PA study unit excluding a small sliver along the Carmel River. The fourth MS-SA study area, Highlands, is composed of the hills and mountains bordering the Salinas Valley. The MS-PA and the MS-SA study units have warm, dry summers and cool, moist winters. The average annual rainfall is 331 millimeters (mm; 13 inches, in.) with average annual temperatures of14 degrees Celsius (57 degrees Fahrenheit) in Salinas. The study units are drained by three main rivers and their tributaries: the Salinas, Pajaro, and San Lorenzo Rivers. Groundwater quality status and understanding assessments of the study units were based on data collected by the U.S. Geological Survey (USGS). In the MS-PA, additional inorganic data was obtained from the California State Water Resources Control BoardDivision of Drinking Water Public- Supply Well Water-Quality Database (Kulongoski and Belitz, 2011). A grid-based method to select wells was applied in both study units, which allows for an estimation of the proportions of the aquifer system with constituents at low, moderate, or high concentrations relative to regulatory and non- regulatory benchmarks for drinking-water quality established by the U.S. Environmental Protection Agency (EPA) or California State Water Resources Control Board Division of Drinking Water. The grid-based method provides statistically unbiased results and permits comparison of those results to other GAMA Priority Basin Project study areas (Belitz and others, 2010).

Delineation of Spatial Extent, Depth, Thickness, and Potential Volume of Aquifers Used for Domestic and Public Water-Supply in the Central Valley, California

U.S. Geological Survey (USGS) | September 5th, 2019

Identification of the groundwater resources used for drinking-water supplies is essential for the design of strategies to manage those resources. In this study, t

Identification of the groundwater resources used for drinking-water supplies is essential for the design of strategies to manage those resources. In this study, the spatial extent, depths, thicknesses, and volumes of groundwater aquifers used for domestic and public drinking-water supply were estimated from locations and well-construction data from 11,725 domestic-supply wells and 2,376 public-supply wells in the Central Valley, California. The data were compiled as part of the U.S. Geological Survey National Water Quality Assessment Project and California State Water Resources Control Board Groundwater Ambient Monitoring and Assessment Program Priority Basin Project. The spatial distributions of the depth to top and bottom of well screens were interpolated using Empirical Bayesian Kriging across buffer areas surrounding domestic- and public-supply wells. These surfaces provide a measure of the likely maximum horizontal and vertical extent of the aquifer volume accessed for drinking water in the Central Valley during the past century. Well depth generally increased from north to south, and over time from 1905 to 2010. Well-construction depths were generally more consistent in the Sacramento Valley than in the San Joaquin Valley. The total potential aquifer volume accessed for public supply was calculated to be greater than domestic-supply access, even though the estimated spatial extent of domestic-supply wells was 1.5 times larger than the spatial extent of public-supply wells. Public-supply wells commonly have screen lengths greater than 51 meters, whereas domestic-supply wells typically have shorter screen lengths (overall median of 6 meters). Consequently, the accessed thickness and volume of the aquifer is on average 1.8 and 1.4 times greater for public-supply wells than domestic- supply wells, respectively. Results are presented as maps of areal extent, depth, and thickness of zones in the Central Valley aquifer system used for domestic and public drinking- water supplies.

Determination of Study Reporting Limits for Pesticide Constituent Data for the California Groundwater Ambient Monitoring and Assessment Program Priority Basin Project, 2004–2018—Part 1: National Water Quality Laboratory Schedules 2003, 2032, or 2033, and 2060

U.S. Geological Survey (USGS) | December 17th, 2019

The California Groundwater Ambient Monitoring and Assessment Program Priority Basin Project (GAMA-PBP) is a long-term cooperative project designed to assess the quality o

The California Groundwater Ambient Monitoring and Assessment Program Priority Basin Project (GAMA-PBP) is a long-term cooperative project designed to assess the quality of groundwater resources used for public and domestic drinking water supplies in the State of California, to monitor and evaluate changes to that quality, to investigate the human and natural factors controlling water quality, and to improve the availability of comprehensive groundwater quality data and information. Between May 18, 2004, and May 3, 2018, the GAMA-PBP collected 3001 groundwater samples for analysis of pesticide constituents by the U.S. Geological Survey (USGS) National Water Quality Laboratory (NWQL)(note that ‘pesticide constituents’ includes parent compounds and degradates). Of these samples, 2994 were analyzed for pesticide constituents on schedules 2003, 2032, or 2033 (65 to 84 constituents), and 840 were analyzed for pesticide constituents on schedule 2060 (58 constituents). The original dataset reported by the NWQL to the USGS National Water Information System (NWIS) database contained a total of 2,688 detections of 78 pesticide constituents and 253,825 non-detections. In this original dataset, 33 percent of the 3,001 samples analyzed had reported detections of one or more pesticide constituents. This report describes the GAMA-PBP data-quality objectives for pesticide data, the procedures used to establish study reporting limits, and use of those reporting limits to censor the data from the NWQL so that the final data published by the GAMA-PBP meet these data-quality objectives. The final GAMA-PBP dataset for samples collected from May 2004 to May 2018, after censoring, had a total of 1,632 detections of 37 pesticide constituents. In the final GAMA-PBP dataset, 25 percent of the 3,001 samples analyzed had detections of one or more pesticide constituents. The presence of pesticides in groundwater is commonly evaluated by calculating detection frequencies. Detection frequencies for pesticides are sensitive to detection limits and method performance for concentrations near those limits; therefore, the two primary data quality issues addressed in the GAMA-PBP data-quality objectives for pesticides are (1) establishing criteria for classifying data from the laboratory as detections or non-detections for the purpose of data reporting by the project and (2) accounting for changes in analytical methods or method performance over time. The GAMA-PBP addresses these issues by developing study reporting limits that are used as the boundary between detections and non-detections for the reporting of GAMA-PBP results. These reporting limits are defined from method detection limits (MDLs) provided by the NWQL, unless examination of results from laboratory set blanks (LSBs) and GAMA-PBP field blanks indicates that a higher concentration censoring limit is warranted. The GAMA-PBP selected the MDL as the primary choice for defining study reporting limits for consistency with U.S. Environmental Protection Agency (EPA) guidelines for reporting detections of pesticides and other organic constituents. A five-step procedure is used to develop study reporting limits and censor the GAMA-PBP dataset accordingly. The effect of the censoring at each step is described to provide information about the relative effect of each step on the overall censoring of the dataset. Steps 1 and 2 can be implemented at the time the data are received, whereas steps 3−5 require information accumulated over an extended period. • Step 1: Reject results that were most likely the result of specific contamination instances attributable to unusual field or laboratory conditions during sample collection or processing. Two such instances were identified, leading to rejection of 25 detections, which were assigned a data-quality indicator code of “Q” for “reviewed and rejected” in the NWIS database. • Step 2: Use the NWQL MDLs in effect at the time each sample was analyzed as the reporting limit. A total of 506 detections were censored on this basis. • Step 3: Use the maximum MDL established by the NWQL during July 2004–August 2018 (MDLmax) as the reporting limit. The rationale for using the MDLmax as the reporting limit is based primarily on the observation that the concentrations of MDLs generally increased over time. A total of 438 detections were censored on this basis. • Step 4: Use the LSBs to identify periods of greater potential laboratory contamination bias and define raised reporting limits to be used during those periods. These periods were defined by using a moving average detection frequency approach. For consistency with the NWQL procedures for defining raised reporting limits on the basis of detections in LSBs, the raised reporting limits were defined as equal to three times the highest concentration measured in an LSB during the period. A total of 25 detections in groundwater samples analyzed during periods of increased laboratory contamination bias were censored. • Step 5: Use the LSBs and field blanks to identify potential contamination bias from field or laboratory processes outside of the time periods identified in step 4. The NWQL protocols were used to define the MDLs from blanks analyzed outside of the periods identified in step 4. If an MDL defined from blanks was greater than the MDLmax, the MDL defined from blanks was used to censor the data. One constituent had a study reporting limit defined on this basis, and a total of 62 detections in groundwater samples were censored. As of 2019, the USGS NWIS database does not have the capability to store both the original value reported by the NWQL and the final value published by the GAMA-PBP that reflects application of the quality-control censoring described in this report. In the interim, while this capability is developed, the 1,031 results censored in steps 2−5 are blocked from public release in NWIS, and the GAMA-PBP has published the original and final values in a USGS data release accompanying this report. The entire GAMA-PBP final dataset for pesticide constituents on schedules 2003, 2032, or 2033, or on schedule 2060 is publicly available in that USGS data release, through the USGS GAMA-PBP public web portal, and through the California State Water Resources Control Board GAMA public groundwater information system.

Effects of Surface-Water Use on Domestic Groundwater Availability and Quality During Drought in the Sierra Nevada Foothills, California

U.S. Geological Survey (USGS) | January 13th, 2020

Approximately 2 million California residents rely on privately owned domestic wells for drinking water. During the California drought of 2012−16 groundwater lev

Approximately 2 million California residents rely on privately owned domestic wells for drinking water. During the California drought of 2012−16 groundwater levels declined in many parts of the state and wells were deepened in response. Most of the wells deepened during this time were domestic wells that were drilled into fractured bedrock throughout the Sierra Nevada foothills region of northern California (California Department of Water Resources, 2014). To understand the impacts of extreme drought on groundwater supply availability and quality in this setting, the United States Geological Survey (USGS) completed a geochemical survey of domestic wells throughout the Yuba and Bear River watersheds during 2015–16 (fig. 1) as part of the State Water Board’s Groundwater Ambient Monitoring and Assessment Program Priority Basin Project (GAMA-PBP). This fact sheet highlights key findings from the GAMA-PBP assessment (Levy and others, 2020).

Geologic Influences on the Quality of Groundwater Used for Domestic Supply in the Northern Sierra Nevada Foothills

U.S. Geological Survey (USGS) | May 25th, 2021

Approximately 2 million California residents depend on groundwater from domestic wells for their drinking-water supply. The State of California, in collaboration with the

Approximately 2 million California residents depend on groundwater from domestic wells for their drinking-water supply. The State of California, in collaboration with the U.S. Geological Survey, created the Groundwater Ambient Monitoring and Assessment Program Priority Basin Project (GAMA-PBP) to assess the quality of groundwater used for domestic supply throughout the state and determine regional vulnerabilities to drinking-water resources. Many rural households in the northern Sierra Nevada foothills (hereafter referred to as “the foothills”) use domestic wells that pump water from fractured-bedrock aquifers. In the foothills, complicated and varied regional bedrock geology can cause substantial variation in groundwater chemistry and quality over relatively short distances. This factsheet presents findings from the GAMA-PBP assessment that highlight influences of geologic factors on groundwater quality in the foothills.

Ground-Water Quality Data in the Middle Sacramento Valley Study Unit, 2006—Results from the California GAMA Program

U.S. Geological Survey (USGS) | July 15th, 2008

Ground-water quality in the approximately 3,340 mi2 Middle Sacramento Valley study unit (MSACV) was investigated from June through September, 2006, as part of the Califor

Ground-water quality in the approximately 3,340 mi2 Middle Sacramento Valley study unit (MSACV) was investigated from June through September, 2006, as part of the California Groundwater Ambient Monitoring and Assessment (GAMA) program. The GAMA Priority Basin Assessment project was developed in response to the Groundwater Quality Monitoring Act of 2001 and is being conducted by the U.S. Geological Survey (USGS) in cooperation with the California State Water Resources Control Board (SWRCB).