Data from Exploratory Sampling of Groundwater in Selected Oil and Gas Areas of Coastal Los Angeles County and Kern and Kings Counties in Southern San Joaquin Valley, 2014–15

U.S. Geological Survey (USGS) | December 9th, 2016

Exploratory sampling of groundwater in coastal Los Angeles County and Kern and Kings Counties of the southern San Joaquin Valley was done by the U.S. Geological Survey fr

Exploratory sampling of groundwater in coastal Los Angeles County and Kern and Kings Counties of the southern San Joaquin Valley was done by the U.S. Geological Survey from September 2014 through January 2015 as part of the California State Water Resources Control Board’s Water Quality in Areas of Oil and Gas Production Regional Groundwater Monitoring Program. The Regional Groundwater Monitoring Program was established in response to the California Senate Bill 4 of 2013 mandating that the California State Water Resources Control Board design and implement a groundwater-monitoring program to assess potential effects of well-stimulation treatments on groundwater resources in California. The U.S. Geological Survey is in cooperation with the California State Water Resources Control Board to collaboratively implement the Regional Groundwater Monitoring Program through the California Oil, Gas, and Groundwater Project. Many researchers have documented the utility of different suites of chemical tracers for evaluating the effects of oil and gas development on groundwater quality. The purpose of this exploratory sampling effort was to determine whether tracers reported in the literature could be used effectively in California. This reconnaissance effort was not designed to assess the effects of oil and gas on groundwater quality in the sampled areas. A suite of water-quality indicators and geochemical tracers were sampled at groundwater sites in selected areas that have extensive oil and gas development. Groundwater samples were collected from a total of 51 wells, including 37 monitoring wells at 17 multiple-well monitoring sites in coastal Los Angeles County and 5 monitoring wells and 9 water-production wells in southern San Joaquin Valley, primarily in Kern and Kings Counties. Groundwater samples were analyzed for field water-quality indicators; organic constituents, including volatile and semi-volatile organic compounds and dissolved organic carbon indicators; naturally present inorganic constituents, including trace elements, nutrients, major and minor ions, and iron species; naturally present stable and radioactive isotopes; dissolved noble gases; dissolved standard and hydrocarbon gases, ?13C of methane, ethane, and ?2H of methane. In total, 249 constituents and water-quality indicators were measured. Four types of quality-control samples (blanks, replicates, matrix spikes, and surrogates spiked in environmental and blank samples) were collected at approximately 10 percent of the wells. The quality-control data were used to determine whether the groundwater-sample data were of sufficient quality for the measured analytes to be used as potential indicators of oil and gas effects. The data from the 51 groundwater samples and from the quality-control samples are presented in this report.

Delta Chromium-53/52 isotopic composition of native and contaminated groundwater, Mojave Desert, USA

Applied Geochemistry (Elsevier) | April 20th, 2012

Chromium(VI) concentrations in groundwater sampled from three contaminant plumes in aquifers in the Mojave Desert near Hinkley, Topock and El Mirage, California, USA, wer

Chromium(VI) concentrations in groundwater sampled from three contaminant plumes in aquifers in the Mojave Desert near Hinkley, Topock and El Mirage, California, USA, were as high as 2600, 5800 and 330 μg/L, respectively. δ53/52Cr compositions from more than 50 samples collected within these plumes ranged from near 0‰ to almost 4‰ near the plume margins. Assuming only reductive fractionation of Cr(VI) to Cr(III) within the plume, apparent fractionation factors for δ53/52Cr isotopes ranged from εapp = 0.3 to 0.4 within the Hinkley and Topock plumes, respectively, and only the El Mirage plume had a fractionation factor similar to the laboratory derived value of ε = 3.5. One possible explanation for the difference between field and laboratory fractionation factors at the Hinkley and Topock sites is localized reductive fractionation of Cr(VI) to Cr(III), with subsequent advective mixing of native and contaminated water near the plume margin. Chromium(VI) concentrations and δ53/52Cr isotopic compositions did not uniquely define the source of Cr near the plume margin, or the extent of reductive fractionation within the plume. However, Cr(VI) and δ53/52Cr data contribute to understanding of the interaction between reductive and mixing processes that occur within and near the margins of Cr contamination plumes. Reductive fractionation of Cr(VI) predominates in plumes having higher εapp, these plumes may be suitable for monitored natural attenuation. In contrast, advective mixing predominates in plumes having lower εapp, the highly dispersed margins of these plumes may be difficult to define and manage.

Estimation of groundwater residence time with deeply-derived carbon mixture considered in California

Science of the Total Environment (Elsevier) | December 16th, 2022

Groundwater has experienced long-term overdraft due to drought and human activities in California, resulting in issues of land subsidence and groundwater anthropogenic co

Groundwater has experienced long-term overdraft due to drought and human activities in California, resulting in issues of land subsidence and groundwater anthropogenic contamination. As a useful indicator of groundwater renewal rate and its residence time, groundwater age has been conventionally investigated based on 14C content and 3H concentration. However, the influence of deeply-derived (endogenic) CO2 mixture is not fully and quantitatively considered, although endogenic carbon contributes a large part of the dissolved inorganic carbon in groundwater. Combined with 3H concentration, both conventional and modified 14C-dating methods with endogenic CO2 mixture considered are employed for groundwater age determination in California. On average, the conventional groundwater 14C apparent age is overestimated by ~4.9 kyr or ~26.2 %, causing groundwater recharge rate underestimation and aquifer recovery time overestimation by ~46.0 % and ~26.2 %, respectively. High 3H concentration indicates modern water mixture in more than one fifth of groundwater samples, including those with high modified 14C apparent age (> 12 kyr, i.e., fossil groundwater) in the Central Valley and southern California, which are generally considered not to be recharged by modern water. Modern water mixture in old groundwater can potentially bring anthropogenic contamination to these groundwater resources, which should be paid attentions by the government and the managers. The results have important implications in evaluation of groundwater replenishment and its susceptibility to modern contamination in California, and in groundwater resources estimation globally.

Evaluation of Processes Affecting 1,2-Dibromo-3-Chloropropane (DBCP) Concentrations in Ground Water in the Eastern San Joaquin Valley, California: Analysis of Chemical Data and Ground-Water Flow and Transport Simulations

U.S. Geological Survey (USGS) | December 17th, 1999

Future use of the sole-source aquifer near Fresno in the eastern San Joaquin Valley, California, will depend, in part, on how long 1,2-dibromo-3-chloropropane (DB

Future use of the sole-source aquifer near Fresno in the eastern San Joaquin Valley, California, will depend, in part, on how long 1,2-dibromo-3-chloropropane (DBCP), an agricultural fumigant banned from use since the late 1970’s, persists at concentrations greater than the maximum contaminant level of 0.2 micrograms per liter (?g/L). Field data indicate that DBCP concentrations in ground water have decreased since the late 1970’s. Laboratory experiments by earlier investigators show that DBCP transformed to 2-bromoallyl alcohol (BAA) under conditions similar to in situ conditions, with an estimated half-life ranging from 6.1 (pH 7.8, 21.1 degrees Celsius) to 141 years (pH 7.0, 15 degrees Celsius). For this current study, a detailed hydrogeologic investigation was done to assess the relative importance of chemical transformation, dispersion, and ground-water pumping and reapplication of irrigation water in affecting DBCP concentrations. Groundwater samples were collected from 20 monitoring wells installed along a 4.6- kilometer transect. DBCP concentrations in these samples ranged from less than the detection limit of 0.03  g/L to a maximum of 6.4 g/L. Results of chlorofluorocarbon (CFC) age dating indicate that DBCP occurs in water that ranges in age from about 2 to 41 years. The primary transformation product BAA, which was identified during previous laboratory studies, was not detected at or greater than 0.03  g/L in any of the 20 ground- water samples. The lack of detection of BAA indicates that transformation to BAA is insignificant relative to other processes controlling DBCP concentrations. Results from this current study indicate that the in situ hydrolysis half-life for DBCP to BAA is much greater than the laboratory-determined values.

Evaluation of the characteristics, discharge, and water quality of selected springs at Fort Irwin National Training Center, San Bernardino County, California

U.S. Geological Survey (USGS) | March 29th, 2024

Eight springs and seeps at Fort Irwin National Training Center were described and categorized by their general characteristics, discharge, geophysical properties, and wat

Eight springs and seeps at Fort Irwin National Training Center were described and categorized by their general characteristics, discharge, geophysical properties, and water quality between 2015 and 2017. The data collected establish a modern (2017) baseline of hydrologic conditions at the springs. Two types of springs were identified: (1) precipitation-fed upland springs (Cave, Desert King, Devouge, No Name, and Panther Springs) and (2) groundwater discharge-fed basin springs (Garlic, Bitter, and Jack Springs). Comparison of electrical resistivity tomography data collected at groundwater basin springs from 2015 to 2017 indicated that spring discharge and connection to the underlying groundwater system is highly focused, although the springs themselves appear diffuse and are spread out over a large area.

Evaluation of the Source and Transport of High Nitrate Concentrations in Ground Water, Warren Subbasin, California

U.S. Geological Survey (USGS) | December 13th, 2003

From early 1995 through 2001, nitrate (NO3) concentrations in ground water in the Warren subbasin, California, increased from a background concentration of 10 milligrams

From early 1995 through 2001, nitrate (NO3) concentrations in ground water in the Warren subbasin, California, increased from a background concentration of 10 milligrams per liter (mg/L) to more than the U.S. Environmental Protection Agency (USEPA) water-quality maximum contaminant level of 44 mg/L (10 mg/L as nitrogen). This increase coincided with an artificial ground-water recharge program implemented by the local water district, Hi-Desert Water District (HDWD), to reverse ground-water level declines of as much as 300 ft. Major findings on ground-water quality from this study are the following: •Septage from septic tanks was the primary source of NO3 to the ground-water system. •Rising ground-water levels, resulting from the artificial-recharge program, entrained high-NO3 septage stored in the unsaturated zone. •The potential for ground-water contamination should be evaluated before beginning an artificial- recharge program in an area that uses septic tanks.

Factors Affecting Public-Supply-Well Vulnerability to Contamination: Understanding Observed Water Quality and Anticipating Future Water Quality

U.S. Geological Survey (USGS) | May 14th, 2013

As part of the U.S. Geological Survey National Water-Quality Assessment (NAWQA) Program, a study was conducted from 2001 to 2011 to shed light on factors that affect the

As part of the U.S. Geological Survey National Water-Quality Assessment (NAWQA) Program, a study was conducted from 2001 to 2011 to shed light on factors that affect the vulnerability of water from public-supply wells to contamination (referred to hereafter as “public-supply-well vulnerability”). The study was designed as a follow-up to earlier NAWQA studies that found mixtures of contaminants at low concentrations in groundwater near the water table in urban areas across the Nation and, less frequently, in deeper groundwater typically used for public supply. Beside the factors affecting public-supply-well vulnerability to contamination, this circular describes measures that can be used to determine which factor (or factors) plays a dominant role at an individual public-supply well. Case-study examples are used throughout to show how such information can be used to improve water quality. In general, the vulnerability of the water from public-supply wells to contamination is a function of contaminant input within the area that contributes water to a well, the mobility and persistence of a contaminant once released to the groundwater, and the ease of groundwater and contaminant movement from the point of recharge to the open interval of a well. The following measures described in this circular are particularly useful for indicating which contaminants in an aquifer might reach an individual public-supply well and when, how, and at what concentration they might arrive: Sources of recharge—Information on the sources of recharge for a well provides insight into contaminants that might enter the aquifer with the recharge water and potentially reach the well. Geochemical conditions—Information on the geochemical conditions encountered by groundwater traveling to a well provides insight into contaminants that might persist in the water all the way to the well. Groundwater-age mixtures—Information on the ages of the different waters that mix in a well provides insight into the time lag between contaminant input at the water table and contaminant arrival at the well. It also provides insight into the potential for in-well dilution of contaminated water by unaffected groundwater of a different age that simultaneously enters the well. Preferential flow pathways—pathways that provide little resistance to flow—can influence how all other factors affect public-supply-well vulnerability to contamination. For example, preferential flow pathways can influence whether a contaminant source is physically linked to a well, whether contaminant concentrations are substantially altered before contaminated groundwater reaches a well, and whether contaminated groundwater can arrive at a well within a timeframe of concern to the well owner. Methods for recognizing the influence of preferential flow pathways on the quality of water from a public-supply well are presented in this circular and can provide opportunities to prevent or mitigate the deterioration of a water supply. Knowing what water-quality variables to measure, what spatial and temporal scales on which to measure them, and how to interpret the resulting data makes it possible for samples from public-supply wells to provide a broad window into a well’s past and present water quality—and possibly future water quality. Such insight can enable resource managers to prioritize actions for sustaining a high-quality groundwater source of drinking water.

Final Environmental Impact Report Volume II: Revised Draft EIR Comprehensive Groundwater Cleanup Strategy for Historical Chromium Discharges from PG&E’s Hinkley Compressor Station, San Bernardino County

California State Water Resources Control Board (SWRCB) | April 20th, 2013

Click here for Volume I.

Click here for Volume I.

Fluid migration pathways to groundwater in mature oil fields: Exploring the roles of water injection/production and oil-well integrity in California, USA

Science of The Total Environment (Elsevier) | August 23rd, 2023

Fourth Five Year Review Report for the San Gabriel Valley Area 2 Superfund Site, Los Angeles, California

U.S. Environmental Protection Agency (EPA) | September 15th, 2022

This is the fourth Five-Year Review of the San Gabriel Valley Area 2 (Site) located in the San Gabriel Valley in Los Angeles County, California. The purpose of this Five-

This is the fourth Five-Year Review of the San Gabriel Valley Area 2 (Site) located in the San Gabriel Valley in Los Angeles County, California. The purpose of this Five-Year Review is to review information to determine if the remedy is and will continue to be protective of human health and the environment. The Site addresses approximately 10 square miles of groundwater contamination in eastern Los Angeles County within the San Gabriel Valley. Groundwater contamination is believed to result from the cumulative impact of decades of improper chemical handling and disposal practices at numerous industrial operations in the Valley. The Site contamination originates at current and former industrial facilities in and near Azusa, California and extends to the southwest through portions of the cities of Irwindale, Baldwin Park, West Covina, and Industry. The most prevalent contaminants in groundwater are trichloroethylene, tetrachloroethylene, carbon tetrachloride, perchlorate, n-nitrosodimethylamine (NDMA), and 1,4-dioxane.