Estuary News, October 2002

San Francisco Estuary Partnership (SFEP) | October 15th, 2002

Estuary News, October 2009

San Francisco Estuary Partnership (SFEP) | October 15th, 2009

Factors Affecting Marsh Vegetation at the Liberty Island Conservation Bank in the Cache Slough Region of the Sacramento–San Joaquin Delta, California

U.S. Geological Survey (USGS) | July 5th, 2017

The Liberty Island Conservation Bank (LICB) is a tidal freshwater marsh restored for the purpose of mitigating adverse effects on sensitive fish populations elsewhere in

The Liberty Island Conservation Bank (LICB) is a tidal freshwater marsh restored for the purpose of mitigating adverse effects on sensitive fish populations elsewhere in the region. The LICB was completed in 2012 and is in the northern Cache Slough region of the Sacramento–San Joaquin Delta. The wetland vegetation at the LICB is stunted and yellow-green in color (chlorotic) compared to nearby wetlands. A study was done to investigate three potential causes of the stunted and chlorotic vegetation: (1) improper grading of the marsh plain, (2) pesticide contamination from agricultural and urban inputs upstream from the site, (3) nitrogen-deficient soil, or some combination of these. Water samples were collected from channels at five sites, and soil samples were collected from four wetlands, including the LICB, during the summer of 2015. Real-time kinematic global positioning system (RTK-GPS) elevation surveys were completed at the LICB and north Little Holland Tract, a closely situated natural marsh that has similar hydrodynamics as the LICB, but contains healthy marsh vegetation. The results showed no significant differences in carbon or nitrogen content in the surface soils or in pesticides in water among the sites. The elevation survey indicated that the mean elevation of the LICB was about 26 centimeters higher than that of the north Little Holland Tract marsh. Because marsh plain elevation largely determines the hydroperiod of a marsh, these results indicated that the LICB has a hydroperiod that differs from that of neighboring north Little Holland Tract marsh. This difference in hydroperiod contributed to the lower stature and decreased vigor of wetland vegetation at the LICB. Although the LICB cannot be regraded without great expense, it could be possible to reduce the sharp angle of the marsh edge to facilitate deeper and more frequent tidal flooding along the marsh periphery. Establishing optimal elevations for restored wetlands is necessary for obtaining the full suite of ecosystem services provided by tidal wetlands. A better system of tidal benchmarks throughout the delta is needed to help restoration practitioners correctly grade the elevation of newly restored wetlands.

Field Assessment of Naled and Its Primary Degradation Product (Dichlorvos) in Aquatic Ecosystems Following Aerial Ultra-low Volume Application for Mosquito Control

Archives of Environmental Contamination and Toxicology (Springer) | March 13th, 2023

Naled, an organophosphate insecticide, is applied aerially at ultra-low volumes over aquatic ecosystems near Sacramento, California, USA, during summer months for mosqui

Naled, an organophosphate insecticide, is applied aerially at ultra-low volumes over aquatic ecosystems near Sacramento, California, USA, during summer months for mosquito control. Two ecosystem types (rice fields and a flowing canal) were sampled in 2020 and 2021. Naled and its primary degradation product (dichlorvos) were measured in water, biofilm, grazer macroinvertebrates, and omnivore/predator macroinvertebrates (predominantly crayfish). Maximum naled and dichlorvos concentrations detected in water samples one day after naled application were 287.3 and 5647.5 ng/L, respectively, which were above the U.S. Environmental Protection Agency’s aquatic life benchmarks for invertebrates. Neither compound was detected in water more than one day after the application. Dichlorvos, but not naled, was detected in composite crayfish samples up to 10 days after the last aerial application. Detections in water from the canal showed that the compounds were transported downstream of the target application area. Factors such as vector control flight paths, dilution, and transport through air and water likely affected concentrations of naled and dichlorvos in water and organisms from these aquatic ecosystems.

Flame retardants and plastic additives in San Francisco Bay: Targeted monitoring of organophosphate esters and bisphenols

San Francisco Estuary Institute (SFEI) | January 31st, 2020

Ground Water in the Central Valley, California - A Summary Report

U.S. Geological Survey (USGS) | June 1st, 1991

The agricultural productivity of the Central Valley depends on irrigation. Half of the 22 million acre-feet of irrigation water applied annually is ground water. The va

The agricultural productivity of the Central Valley depends on irrigation. Half of the 22 million acre-feet of irrigation water applied annually is ground water. The valley is a long, narrow structural trough filled with about 32,000 feet of sediment in the south and as much as 50,000 feet in the north. Nearly all the fresh ground water is contained in the continental rocks and deposits younger than Eocene age. Streamflow, an important factor in recharging the aquifer system, is influenced by precipitation in the mountains surrounding the valley. The majority of recharge from infiltration of streamflow occurs on the east side of the valley. Ground-water pumpage, which greatly exceeds the natural recharge rate, has dramatically altered the ground-water flow in the Central Valley. During the 1960's and 1970's, the recharge rate was more than five times that of the predevelopment period and was largely derived from percolation of imported surface water or recirculated pumped ground water rather than precipitation and recharge from streams. Prior to development, most ground water was discharged as evapotranspiration; however, in recent years, most discharge has been well pumpage. Computer simulation of the Central Valley aquifer system suggests that the total flow through the system has increased from about 2 million acre-feet per year to nearly 12 million acre-feet per year. The vertical movement of ground water has been artificially enhanced by many of the 100,000 irrigation wells that contain long intervals of perforated casing. When unpumped, these wells permit vertical flow between permeable layers within the aquifer system. The total fresh ground water presently (1986) in storage in the upper 1,000 feet of the aquifer system is about 800 million acre-feet. During the 1960's and 1970's, ground water in storage was depleted at an average rate of 800,000 acre-feet annually. In the San Joaquin Valley from the 1940's to the late 1960's, substantial withdrawals of ground water were accompanied by hundreds of feet of head decline. This head decline caused inelastic compaction of fine-grained beds, resulting in land subsidence that is unequaled anywhere else in the world. More than one-half of the San Joaquin Valley (or about 5,200 square miles) underwent subsidence of more than 1 foot. In one location, subsidence exceeded 29 feet. Within the areas of heavy withdrawals, subsidence is greatest where the aquifer system contains thick sections of montmorillonite clay. Land subsidence created engineering and economic problems, including damage to canals and drainage systems, and loss of irrigation wells caused by casing failure. More recently (since the drought of 1976-77), surface-water imports have increased, ground-water pumpage has decreased, and in places, ground-water levels have recovered. Land subsidence has virtually ceased; however, it could resume with increased pumpage, if water levels decline below previous lows. Ground-water quality in the Central Valley is generally influenced by the water from streams that are a major source of recharge. In general, water on the east side of the valley and from east-side streams contains low concentrations of dissolved solids compared to water on the west side and from west-side streams. Concentrations of dissolved solids in ground water generally are lower in the northern part of the valley than in the southern part. There are, however, localized exceptions in many places through the valley. Local concentrations of boron, chloride, and nitrate in the ground water of the Central Valley are large enough to be a problem either to crops or humans. Human activities have some influence on the concentration and location of water-quality problems in the valley. Significant increases in concentrations of dissolved solids and, specifically, dissolved nitrate indicate that ground-water quality is degrading as a result of increasing application of fertilizer in agricultural areas and the growth of urban population. Pesticides such as dibromochloropropane (DBCP) as well as selenium and other trace elements in agricultural drainage water cause ecological and health problems in the San Joaquin Valley.

Healthy, Fair, and Profitable: A Win-Win Pesticide Policy

Pacific Institute | January 1st, 2002

A new report released by the Pacific Institute and the California Green Scissors project makes the case for changing the way pesticides are regulated in California. Acc

A new report released by the Pacific Institute and the California Green Scissors project makes the case for changing the way pesticides are regulated in California. According to the report, if California significantly increased its funding for sustainable agriculture — instead of just spending money to regulate pesticide usage — we could aid California farmers, improve the public health and save millions of dollars in associated costs.

History and Sources of Co-Occurring Pesticides in an Abstraction Well Unraveled by Age Distributions of Depth-Specific Groundwater Samples

American Chemical Society (ACS) | November 24th, 2019

When groundwater-based drinking water supply becomes contaminated, the timing and source of contamination are obvious questions. However, contaminants often have diffuse

When groundwater-based drinking water supply becomes contaminated, the timing and source of contamination are obvious questions. However, contaminants often have diffuse sources and different contaminants may have different sources even in a single groundwater well, making these questions complicated to answer. Age dating of groundwater has been used to reconstruct contaminant travel times to wells; however, critics have highlighted that groundwater flow is often complex with mixing of groundwater of different ages. In drinking water wells, where water is typically abstracted from a large depth interval, such mixing is even more problematic. We present a way to overcome some of the obstacles in identifying the source and age of contaminants in drinking water wells by combining depth-specific sampling with age tracer modeling, particle tracking simulations, geological characterization, and contaminant properties. This multitool approach was applied to a drinking water well, where bentazon and dichlorprop contamination was found to have different pollutant sources and release histories, even though both pesticides can be associated with the same land use. Bentazon was derived from recent application to a golf course, while dichlorprop was derived from agricultural use more than 30 years ago. The advantages, limitations, and pitfalls of the proposed course of action are then further discussed.

History and Sources of Co-Occurring Pesticides in an Abstraction Well Unraveled by Age Distributions of Depth-Specific Groundwater Samples

American Chemical Society (ACS) | November 24th, 2019

When groundwater-based drinking water supply becomes contaminated, the timing and source of contamination are obvious questions. However, contaminants often have diffuse

When groundwater-based drinking water supply becomes contaminated, the timing and source of contamination are obvious questions. However, contaminants often have diffuse sources and different contaminants may have different sources even in a single groundwater well, making these questions complicated to answer. Age dating of groundwater has been used to reconstruct contaminant travel times to wells; however, critics have highlighted that groundwater flow is often complex with mixing of groundwater of different ages. In drinking water wells, where water is typically abstracted from a large depth interval, such mixing is even more problematic. We present a way to overcome some of the obstacles in identifying the source and age of contaminants in drinking water wells by combining depth-specific sampling with age tracer modeling, particle tracking simulations, geological characterization, and contaminant properties. This multitool approach was applied to a drinking water well, where bentazon and dichlorprop contamination was found to have different pollutant sources and release histories, even though both pesticides can be associated with the same land use. Bentazon was derived from recent application to a golf course, while dichlorprop was derived from agricultural use more than 30 years ago. The advantages, limitations, and pitfalls of the proposed course of action are then further discussed.

Inclusion of Pesticide Transformation Products Is Key to Estimating Pesticide Exposures and Effects in Small U.S. Streams

American Chemical Society (ACS) | March 10th, 2021

Improved analytical methods can quantify hundreds of pesticide transformation products (TPs), but understanding of TP occurrence and potential toxicity in aquatic ecosyst

Improved analytical methods can quantify hundreds of pesticide transformation products (TPs), but understanding of TP occurrence and potential toxicity in aquatic ecosystems remains limited. We quantified 108 parent pesticides and 116 TPs in more than 3 700 samples from 442 small streams in mostly urban basins across five major regions of the United States. TPs were detected nearly as frequently as parents (90 and 95% of streams, respectively); 102 TPs were detected at least once and 28 were detected in >20% samples in at least one region—TPs of 9 herbicides, 2 fungicides (chlorothalonil and thiophanate-methyl), and 1 insecticide (fipronil) were the most frequently detected. TPs occurred commonly during baseflow conditions, indicating chronic environmental TP exposures to aquatic organisms and the likely importance of groundwater as a TP source. Hazard quotients based on acute aquatic-life benchmarks for invertebrates and nonvascular plants and vertebrate-centric molecular endpoints (sublethal effects) quantify the range of the potential contribution of TPs to environmental risk and highlight several TP exposure–response data gaps. A precautionary approach using equimolar substitution of parent benchmarks or endpoints for missing TP benchmarks indicates that potential aquatic effects of pesticide TPs could be underestimated by an order of magnitude or more.