Geologic Map and Borehole Stratigraphy of Hinkley Valley and Vicinity, San Bernardino County, California

U.S. Geological Survey (USGS) | December 17th, 2020

Hinkley Valley, in the central to western Mojave Desert of southeastern California, has a long historical record owing to its position as a crossroads for rail and road t

Hinkley Valley, in the central to western Mojave Desert of southeastern California, has a long historical record owing to its position as a crossroads for rail and road traffic and its position adjacent to the Mojave River. Subflow in the Mojave River provided groundwater recharge that maintained water consumption and demand by way of shallow wells for local agriculture (Thompson, 1929) in the valley. Its crossroads position led to construction of several power-transmission lines, pipeline, and communications cable routes that transect Hinkley Valley. One of these, a natural gas pipeline and its associated compressor station, was the locus of hexavalent chromium, Cr(VI), releases into, and consequent contamination of, groundwater (Izbicki and Groover, 2018). Understanding the movement and fate of the contaminants is a complex hydrologic and geo-chemical problem. Geologic mapping of the Hinkley Valley area provides framework elements for use in resolving this problem.

Geologic, Hydrologic, and Water-Quality Data From Multiple-Well Monitoring Sites in the Bunker Hill and Yucaipa Groundwater Subbasins, San Bernardino County, California, 1974–2016

U.S. Geological Survey (USGS) | October 31st, 2018

In 1974, the U.S. Geological Survey (USGS), in cooperation with the San Bernardino Valley Municipal Water District, initiated a study to assess the regional groun

In 1974, the U.S. Geological Survey (USGS), in cooperation with the San Bernardino Valley Municipal Water District, initiated a study to assess the regional groundwater resources in the Bunker Hill Subbasin of the Upper Santa Ana Valley Groundwater Basin in San Bernardino County, California. The study area expanded east into the Yucaipa Subbasin in 1996. This report compiles the geologic (borehole lithology and geophysical logs) and hydrologic (water- quality and water-level) data collected from 1974–2016 for 11 multiple-well monitoring sites (48 individual wells) constructed by the USGS in the Bunker Hill (7 sites) and Yucaipa (4 sites) Groundwater Subbasins. Approximately 240 water-quality samples from the 11 sites were analyzed for constituents including major and minor ions, nutrients, selected trace elements, organic wastewater compounds (OWCs), volatile organic compounds (VOCs), pesticides and pesticide degradates, the stable isotopes of hydrogen, oxygen, and nitrogen, and the radiogenic isotopes of tritium and carbon-14. All environmental data associated with these sites are available on the project web page for the San Bernardino Optimal Basin Management study and the Yucaipa Valley Hydrogeology study. Quality-assurance blank samples were processed periodically throughout the study and show that approximately 2.4 percent of the analytical results for major and minor ions, trace elements, and nutrients, and 1.5 percent of the results for VOCs fall below the acceptable study reporting limits and therefore are censored.

Global aquifers dominated by fossil groundwaters but wells vulnerable to modern contamination

Nature Portfolio (Springer Nature) | July 25th, 2017

The vulnerability of groundwater to contamination is closely related to its age. Groundwaters that infiltrated prior to the Holocene have been documented in many aquifers

The vulnerability of groundwater to contamination is closely related to its age. Groundwaters that infiltrated prior to the Holocene have been documented in many aquifers and are widely assumed to be unaffected by modern contamination. However, the global prevalence of these ‘fossil’ groundwaters and their vulnerability to modern-era pollutants remain unclear. Here we analyse groundwater carbon isotope data (12C, 13C, 14C) from 6,455 wells around the globe. We show that fossil groundwaters comprise a large share (42–85%) of total aquifer storage in the upper 1?km of the crust, and the majority of waters pumped from wells deeper than 250m. However, half of the wells in our study that are dominated by fossil groundwater also contain detectable levels of tritium, indicating the presence of much younger, decadal-age waters and suggesting that contemporary contaminants may be able to reach deep wells that tap fossil aquifers. We conclude that water quality risk should be considered along with sustainable use when managing fossil groundwater resources.

Ground Water Flow in a Desert Basin: Challenges of Simulating Transport of Dissolved Chromium

National Groundwater Association (NGWA) | December 13th, 2005

A large chromium plume that evolved from chromium releases in a valley near the Mojave River was studied to understand the processes controlling fate and migration of chr

A large chromium plume that evolved from chromium releases in a valley near the Mojave River was studied to understand the processes controlling fate and migration of chromium in ground water and used as a tracer to study the dynamics of a basin and range ground water system. The valley that was studied is naturally arid with high evapotranspiration such that essentially no precipitation infiltrates to the water table. The dominant natural hydrogeologic processes are recharge to the ground water system from the Mojave River during the infrequent episodes when there is flow in the river, and ground water flow toward a playa lake where the ground water evaporates. Agricultural pumping in the valley from the mid‐1930s to the 1970s significantly altered ground water flow conditions by decreasing water levels in the valley by more than 20 m. This pumping declined significantly as a result of dewatering of the aquifer, and water levels have since recovered modestly. The ground water system was modeled using MODFLOW, and chromium transport was simulated using MT3D. Several innovative modifications were made to these modeling programs to simulate important processes in this ground water system. Modifications to MODFLOW include developing a new well package that estimates pumping rates from irrigation wells at each time step based on available drawdown. MT3D was modified to account for mass trapped above the water table when the water table declines beneath nonirrigated areas and to redistribute mass to the system when water levels rise.

Ground Water in the Central Valley, California - A Summary Report

U.S. Geological Survey (USGS) | June 1st, 1991

The agricultural productivity of the Central Valley depends on irrigation. Half of the 22 million acre-feet of irrigation water applied annually is ground water. The va

The agricultural productivity of the Central Valley depends on irrigation. Half of the 22 million acre-feet of irrigation water applied annually is ground water. The valley is a long, narrow structural trough filled with about 32,000 feet of sediment in the south and as much as 50,000 feet in the north. Nearly all the fresh ground water is contained in the continental rocks and deposits younger than Eocene age. Streamflow, an important factor in recharging the aquifer system, is influenced by precipitation in the mountains surrounding the valley. The majority of recharge from infiltration of streamflow occurs on the east side of the valley. Ground-water pumpage, which greatly exceeds the natural recharge rate, has dramatically altered the ground-water flow in the Central Valley. During the 1960's and 1970's, the recharge rate was more than five times that of the predevelopment period and was largely derived from percolation of imported surface water or recirculated pumped ground water rather than precipitation and recharge from streams. Prior to development, most ground water was discharged as evapotranspiration; however, in recent years, most discharge has been well pumpage. Computer simulation of the Central Valley aquifer system suggests that the total flow through the system has increased from about 2 million acre-feet per year to nearly 12 million acre-feet per year. The vertical movement of ground water has been artificially enhanced by many of the 100,000 irrigation wells that contain long intervals of perforated casing. When unpumped, these wells permit vertical flow between permeable layers within the aquifer system. The total fresh ground water presently (1986) in storage in the upper 1,000 feet of the aquifer system is about 800 million acre-feet. During the 1960's and 1970's, ground water in storage was depleted at an average rate of 800,000 acre-feet annually. In the San Joaquin Valley from the 1940's to the late 1960's, substantial withdrawals of ground water were accompanied by hundreds of feet of head decline. This head decline caused inelastic compaction of fine-grained beds, resulting in land subsidence that is unequaled anywhere else in the world. More than one-half of the San Joaquin Valley (or about 5,200 square miles) underwent subsidence of more than 1 foot. In one location, subsidence exceeded 29 feet. Within the areas of heavy withdrawals, subsidence is greatest where the aquifer system contains thick sections of montmorillonite clay. Land subsidence created engineering and economic problems, including damage to canals and drainage systems, and loss of irrigation wells caused by casing failure. More recently (since the drought of 1976-77), surface-water imports have increased, ground-water pumpage has decreased, and in places, ground-water levels have recovered. Land subsidence has virtually ceased; however, it could resume with increased pumpage, if water levels decline below previous lows. Ground-water quality in the Central Valley is generally influenced by the water from streams that are a major source of recharge. In general, water on the east side of the valley and from east-side streams contains low concentrations of dissolved solids compared to water on the west side and from west-side streams. Concentrations of dissolved solids in ground water generally are lower in the northern part of the valley than in the southern part. There are, however, localized exceptions in many places through the valley. Local concentrations of boron, chloride, and nitrate in the ground water of the Central Valley are large enough to be a problem either to crops or humans. Human activities have some influence on the concentration and location of water-quality problems in the valley. Significant increases in concentrations of dissolved solids and, specifically, dissolved nitrate indicate that ground-water quality is degrading as a result of increasing application of fertilizer in agricultural areas and the growth of urban population. Pesticides such as dibromochloropropane (DBCP) as well as selenium and other trace elements in agricultural drainage water cause ecological and health problems in the San Joaquin Valley.

Ground-water Quality in the Lompoc Plain, Santa Barbara County, California, 1983

U.S. Geological Survey (USGS) | June 13th, 1988

This report summarizes the results of a comprehensive study of ground-water quality in the Lompoc plain in western Santa Barbara County. Water-quality characteristics

This report summarizes the results of a comprehensive study of ground-water quality in the Lompoc plain in western Santa Barbara County. Water-quality characteristics in 1983 are described, and changes in water quality since the last comprehensive study in the early 1970's are documented. Ground water is the main source of water in the Lompoc plain. The younger alluvium is the major aquifer and consists predominantly of unconsolidated deposits of sand and gravel. The younger alluvium is as much as 180 feet thick and is divided into an upper member and a lower member throughout most of the plain. The lower member is the main water-bearing zone in the Lompoc plain. Long-term ground-water levels in most of the plain have not changed significantly since the 1940's. A seasonal water-level decline of about 15 feet in 1982 in the central part of the plain may be attributed to nearby military and agricultural pumping. Ground-water quality in the plain in 1983 tended to deteriorate from east to west. Dissolved-solids concentrations throughout the plain exceeded the U.S. Environmental Protection Agency secondary maximum contaminant level of 500 milligrams per liter for drinking water; in most of the plain, concentrations exceeded 1,000 milligrams per liter. In samples from some wells, concentrations of one or more of the following constituents sodium, chloride, nitrate, and iron exceeded primary or secondary maximum contaminant levels for drinking water. Concentrations of constituents in some samples also exceeded recommended levels for irrigation water. The predominant ions generally were calcium, magnesium, sulfate, and bicarbonate - except in the western part, where sodium and chloride were the predominant dissolved ions. From 1972 to 1983, dissolved-solids concentrations in the main water-bearing zone generally decreased in the central part of the plain but increased throughout most of the study area. The largest increases, greater than 1,000 milligrams per liter, were in the extreme western part of the plain.

Groundwater Contributions of Flow, Nitrate, and Dissolved Organic Carbon to the Lower San Joaquin River, California, 2006–08

U.S. Geological Survey (USGS) | October 8th, 2013

The influence of groundwater on surface-water quality in the San Joaquin River, California, was examined for a 59-mile reach from the confluence with Salt Slough to Verna

The influence of groundwater on surface-water quality in the San Joaquin River, California, was examined for a 59-mile reach from the confluence with Salt Slough to Vernalis. The primary objective of this study was to quantify the rate of groundwater discharged to the lower San Joaquin River and the contribution of nitrate and dissolved organic carbon concentrations to the river. Multiple lines of evidence from four independent approaches were used to characterize groundwater contributions of nitrogen and dissolved organic carbon. Monitoring wells (in-stream and bank wells), streambed synoptic surveys (stream water and shallow groundwater), longitudinal profile surveys by boat (continuous water-quality parameters in the stream), and modeling (MODFLOW and VS2DH) provided a combination of temporal, spatial, quantitative, and qualitative evidence of groundwater contributions to the river and the associated quality. Monitoring wells in nested clusters in the streambed (in-stream wells) and on both banks (bank wells) along the river were monitored monthly from September 2006 to January 2009. Nitrate concentrations in the bank wells ranged from less than detection—that is, less than 0.01 milligrams per liter (mg/L) as nitrogen (N)—to approximately 13 mg/L as N. Nitrate was not detected at 17 of 26 monitoring wells during the study period. Dissolved organic carbon concentrations among monitoring wells were highly variable, but they generally ranged from 1 to 4 mg/L. In a previous study, 14 bank wells were sampled once in 1988 following their original installation. With few exceptions, specific conductivity and nitrate concentrations measured in this study were virtually identical to those measured 20 years ago. Streambed synoptic measurements were made by using a temporarily installed drive-point piezometer at 113 distinct transects across the stream during 4 sampling events. Nitrate concentrations exceeded the detection limit of 0.01 mg/L as N in 5 percent of groundwater samples collected from the in-stream wells as part of the synoptic surveys. Only 7 of the 113 cross-sectional transects had nitrate concentrations greater than 1 mg/L as N. In contrast, surface waters in the San Joaquin River tended to have nitrate concentrations in the 1–3 mg/L as N range. A zone of lower oxygen (less than 2 mg/L) in the streambed could limit nitrate contributions from regional groundwater flow because nitrate can be converted to nitrogen gas within this zone. Appreciable concentrations of ammonium (average concentration was 1.92 mg/L as N, and 95th percentile was 10.34 mg/L as N) in the shallow groundwater, believed to originate from anoxic mineralization of streambed sediments, could contribute nitrogen to the overlying stream as nitrate following in-stream nitrification, however. Dissolved organic carbon concentrations were highly variable in the shallow groundwater below the river (1 to 6 ft below streambed) and generally ranged between 1 and 5 mg/L, but had maximum concentrations in the 15–25 mg/L range. The longitudinal profile surveys were not particularly useful in identifying groundwater discharge areas. However, the longitudinal approach described in this report was useful as a baseline survey of measured water-quality parameters and for identifying tributary inflows that affect surface-water concentrations of nitrate. Results of the calibrated MODFLOW model indicated that the simulated groundwater discharge rate was approximately 1.0 cubic foot per second per mile (cfs/mi), and the predominant horizontal groundwater flow direction between the deep bank wells was westward beneath the river. The modeled (VS2DH) flux values (river gain versus river loss) were calculated for the irrigation and non-irrigation season, and these fluxes were an order of magnitude less than those from MODFLOW. During the irrigation season, the average river gain was 0.11 cfs/mi, and the average river loss was ?0.05 cfs/mi. During the non-irrigation season, the average river gain was 0.10 cfs/mi, and the average river loss was 0.08 cfs/mi.

Groundwater Quality Data for the Madera/Chowchilla–Kings Shallow Aquifer Study Unit, 2013–14: Results from the California GAMA Program

U.S. Geological Survey (USGS) | February 2nd, 2017

Groundwater quality in the 2,390-square-mile Madera/Chowchilla–Kings Shallow Aquifer study unit was investigated by the U.S. Geological Survey from August 2013 to April

Groundwater quality in the 2,390-square-mile Madera/Chowchilla–Kings Shallow Aquifer study unit was investigated by the U.S. Geological Survey from August 2013 to April 2014 as part of the California State Water Resources Control Board Groundwater Ambient Monitoring and Assessment Program’s Priority Basin Project. The study was designed to provide a statistically unbiased, spatially distributed assessment of untreated groundwater quality in the shallow aquifer systems of the Madera, Chowchilla, and Kings subbasins of the San Joaquin Valley groundwater basin. The shallow aquifer system corresponds to the part of the aquifer system generally used by domestic wells and is shallower than the part of the aquifer system generally used by public-supply wells. This report presents the data collected for the study and a brief preliminary description of the results. Groundwater samples were collected from 77 wells and were analyzed for organic constituents, inorganic constituents, selected isotopic and age-dating tracers, and microbial indicators. Most of the wells sampled for this study were private domestic wells. Unlike groundwater from public-supply wells, the groundwater from private domestic wells is not regulated for quality in California and is rarely analyzed for water-quality constituents. To provide context for the sampling results, however, concentrations of constituents measured in the untreated groundwater were compared with regulatory and non-regulatory benchmarks established for drinking-water quality by the U.S. Environmental Protection Agency, the State of California, and the U.S. Geological Survey. Of the 319 organic constituents assessed in this study (90 volatile organic compounds and 229 pesticides and pesticide degradates), 17 volatile organic compounds and 23 pesticides and pesticide degradates were detected in groundwater samples; concentrations of all but 2 were less than the respective benchmarks. The fumigants 1,2-dibromo-3-chloropropane (DBCP) and 1,2-dibromoethane (EDB) were detected at concentrations above their respective regulatory benchmarks in samples from a total of four wells. Most detections of inorganic constituents were at concentrations or activities less than the respective benchmark levels. Five inorganic constituents were detected in groundwater samples from one or more wells at concentrations or activities greater than their respective regulatory, health-based benchmarks: arsenic, uranium, nitrate, adjusted gross alpha particle activity, and gross beta particle activity. Four inorganic constituents were detected in samples from one or more wells at concentrations or activities greater than their respective non-regulatory, health-based benchmarks: manganese, molybdenum, vanadium, and radon-222. Three inorganic constituents were detected in groundwater samples from one or more wells at concentrations greater than their respective non-regulatory, aesthetic-based benchmarks: iron, sulfate, and total dissolved solids. Microbial indicators (Escherichia coli, total coliform, and enterococci) were analyzed for presence or absence. The presence of Escherichia coli (E. coli) was not detected; the presence of total coliform was detected in samples from 10 of the 72 grid wells for which it was analyzed, and the presence of enterococci was detected in samples from 5 of the 73 grid wells analyzed.

Groundwater quality data in the Mojave study unit, 2008: Results from the California GAMA Program

U.S. Geological Survey (USGS) | July 1st, 2009

Groundwater Quality in Coachella Valley, California

U.S. Geological Survey (USGS) | January 9th, 2013

Groundwater provides more than 40 percent of California’s drinking water. To protect this vital resource, the State of California created the Groundwater Ambient Monito

Groundwater provides more than 40 percent of California’s drinking water. To protect this vital resource, the State of California created the Groundwater Ambient Monitoring and Assessment (GAMA) Program. The Priority Basin Project of the GAMA Program provides a comprehensive assessment of the State’s groundwater quality and increases public access to groundwater-quality information. Coachella Valley is one of the study areas being evaluated. The Coachella study area is approximately 820 square miles (2,124 square kilometers) and includes the Coachella Valley groundwater basin (California Department of Water Resources, 2003). Coachella Valley has an arid climate, with average annual rainfall of about 6 inches (15 centimeters). The runoff from the surrounding mountains drains to rivers that flow east and south out of the study area to the Salton Sea. Land use in the study area is approximately 67 percent (%) natural, 21% agricultural, and 12% urban. The primary natural land cover is shrubland. The largest urban areas are the cities of Indio and Palm Springs (2010 populations of 76,000 and 44,000, respectively). Groundwater in this basin is used for public and domestic water supply and for irrigation. The main water-bearing units are gravel, sand, silt, and clay derived from surrounding mountains. The primary aquifers in Coachella Valley are defined as those parts of the aquifers corresponding to the perforated intervals of wells listed in the California Department of Public Health database. Public-supply wells in Coachella Valley are completed to depths between 490 and 900 feet (149 to 274 meters), consist of solid casing from the land surface to a depth of 260 to 510 feet (79 to 155 meters), and are screened or perforated below the solid casing. Recharge to the groundwater system is primarily runoff from the surrounding mountains, and by direct infiltration of irrigation. The primary sources of discharge are pumping wells, evapotranspiration, and underflow to the Salton Sea and Imperial Valley areas.